Some factors affecting the synthesis of ZIF-94 from zinc sulfate hetahydrate

Trinh Thi Hai; Pham Thi Mai Huong; Ta Ngoc Thien Huy; Duong Ngoc Lam; Pham Quang Huy; Nguyen Sy Tuan; Nguyen Xuan Thong; Nguyen Huong Giang; Le Van Duong; Ta Ngoc Don

doi:10.62239/jca.2024.078

Some factors affecting the synthesis of ZIF-94 from zinc sulfate hetahydrate

Authors

Trinh Thi Hai Hanoi University of Industry Author
Pham Thi Mai Huong Hanoi University of Industry Author
Ta Ngoc Thien Huy Kien Giang University Author
Duong Ngoc Lam Hanoi University of Industry Author
Pham Quang Huy Hanoi University of Industry Author
Nguyen Sy Tuan School of Chemistry and Life Sciences, Hanoi University of Science and Technology Author
Nguyen Xuan Thong School of Chemistry and Life Sciences, Hanoi University of Science and Technology Author
Nguyen Huong Giang School of Chemistry and Life Sciences, Hanoi University of Science and Technology Author
Le Van Duong School of Chemistry and Life Sciences, Hanoi University of Science and Technology Author
Ta Ngoc Don School of Chemistry and Life Science, Hanoi University of Science and Technology Author

DOI:

https://doi.org/10.62239/jca.2024.078

Keywords:

ZIF-94, SIM-1, zinc nitrate hexahydrate, synthesis, characterization

Abstract

The paper presents the first research results on the synthesis of ZIF-94 from ZnSO₄.7H₂O and some factors affecting the formation of ZIF-94. In this study, XRD method was used to study the crystallinity and particle size through the Scherrer equation. Nitrogen adsorption and desorption method, SEM and TEM were also used to determine the characteristics of the synthesized ZIF-94.

The research results showed that the linker, solvent, additives in the reaction components, crystallization time and temperature have significant effects on the formation of ZIF-94. Suitable conditions were also discussed for the formation of ZIF-94 with BET specific surface of 709 m²/g, average particle size of 55 nm (by SEM) and crystallinity of 100 % (by XRD).

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Published

30-12-2024

Issue

Vol. 13 No. 4 (2024): December

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Full Articles

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How to Cite

Some factors affecting the synthesis of ZIF-94 from zinc sulfate hetahydrate. (2024). Vietnam Journal of Catalysis and Adsorption, 13(4), 79-84. https://doi.org/10.62239/jca.2024.078