Reduction of 4-nitrophenol to 4-aminophenol using Pt/HKUST-1 catalyst

Bui Thi Thanh Ha; Le Van Duong; Ta Ngoc Hung; Dinh Thi Thanh Hai; Pham Dai Duong; Nguyen Le Anh; Ta Ngoc Don

doi:10.51316/jca.2022.017

Authors

Bui Thi Thanh Ha Hanoi University of Pharmacy Author
Le Van Duong School of Chemical Engineering, Hanoi University of Science and Technology, Vietnam Author
Ta Ngoc Hung Deakin University, Australia Author
Dinh Thi Thanh Hai Hanoi University of Pharmacy Author
Pham Dai Duong Joint Vietnam-Russia Tropical Author
Nguyen Le Anh High School for Gifted Students, Hanoi National University of Education Author
Ta Ngoc Don School of Chemical Engineering, Hanoi University of Science and Technology, Vietnam Author

DOI:

https://doi.org/10.51316/jca.2022.017

Keywords:

HKUST-1, MOFS-199, Metal Organic Frameworks (MOFs), 4-nitrophenol, NaBH4, 4-aminophenol, paracetamol

Abstract

The catalyst Pt/HKHUST-1 was used for synthesis 4-aminophenol (4-AP) by reducsion 4-nitrophenol (4-NP). Factors that affected to the reaction were tested: ratio 4-NP/NaBH₄, temperature and time of the reaction. Changing the ratio of 4-NP/NaBH₄ in the direction of increasing NaBH₄, the reaction rate increases. However, it is acceptable to reduce the reaction rate when synthesizing with high concentration of reactants. The 4-AP synthesis is performed with ratio 4-NP/NaBH₄ = 1/5, suitable time and temperature for this reaction is 60 minutes and 15 ^oC. The catalyst sample containing 2% Pt on HKUST-1 material was used to synthesize 4-AP with the yield of 65.3% (average 64.2%), the catalyst has good stability, can reused many times. The purity of 4-AP after refining was > 99 %.

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