Photocatalytic Degradation of Alpha Cypermethrin Based on ZSM-5/TiO2 Hybrid Composites

Tran Thi Ngoc My; Dan-Thuy Van-Pham; Tran Thi Bich Quyen; Ngo Truong Ngoc Mai; Ta Ngoc Don; Doan Van Hong Thien

doi:10.51316/jca.2022.044

Authors

Tran Thi Ngoc My Department of Chemical Engineering, Can Tho University–3/2 Street, Ninh Kieu District, Can Tho City, Vietnam Author
Dan-Thuy Van-Pham Department of Chemical Engineering, Can Tho University–3/2 Street, Ninh Kieu District, Can Tho City, Vietnam Author
Tran Thi Bich Quyen Department of Chemical Engineering, Can Tho University–3/2 Street, Ninh Kieu District, Can Tho City, Vietnam Author
Ngo Truong Ngoc Mai Department of Chemical Engineering, Can Tho University–3/2 Street, Ninh Kieu District, Can Tho City, Vietnam Author
Ta Ngoc Don School of Chemical Engineering, Hanoi University of Science and Technology, Hanoi, Vietnam Author
Doan Van Hong Thien Department of Chemical Engineering, Can Tho University–3/2 Street, Ninh Kieu District, Can Tho City, Vietnam Author

DOI:

https://doi.org/10.51316/jca.2022.044

Keywords:

alpha – cypermethrin, TiO2 nanoparticles, photocatalysis, ZSM-5

Abstract

Zeolite Socony Mobil-5 (ZSM-5) was successfully synthesized by a hydrothermal method from the silicon dioxide (SiO₂) precursor prepared from rice husk ash. Titanium dioxide (TiO₂) nanoparticles were decorated on ZSM-5 substrate by a sol-gel method. ZSM-5/TiO₂ materials were characterized by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), transmission electron microscope (TEM), and Brunauer-Emmett-Teller (BET) surface area analysis. ZSM-5 was successfully synthesized in crystal structure with an average crystallite size of 3-5 mm. TiO₂ nanoparticles with the size of 3-5 nm were distributed on the surface of ZSM-5. ZSM-5/TiO₂materials were used as a photocatalyst to remove alpha – cypermethrin, a kind of the pesticide residues. The results showed that the removal efficiency was 90% with the initial concentration of alpha - cypermethrin of 160 mg L^-1. ZSM-5/TiO₂ would be a very potential material for using as a photocatalyst for the treatment of persistent organic pollutants.

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