Effect of Mn2+ dopants on the photocatalytic efficiency of MoS2
DOI:
https://doi.org/10.51316/jca.2020.039Keywords:
MoS2, Mn doped MoS2, Rhodamine B, photocatalytic degradation, visible lightAbstract
The Mn-doped MoS2 (Mn-MoS2) material is fabricated by a facile one-step calcination method. The Mn2+ content introduced into MoS2 is ranged from 1 wt% to 7 wt%. The X-ray diffraction (XRD) and scanning electron microscopy SEM results suggest that the doping of Mn2+ does not alter the crystal structure and the morphology of MoS2. However, it helps the Mn-doped MoS2 to exhibit stronger visible light absorption and higher magnetism. Especially, in the RhB degradation under visible light irradiation, better photocatalytic performance of the as-prepared Mn-doped MoS2 is observed compared to that of pure MoS2.
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Zhenyin Hai, Jiangong Du, Mohammad Karbalaei Akbari, Chenyang Xue, Hongyan Xu & Serge Zhuiykov, Carbon-doped MoS2 nanosheets photocatalysts for efficient degradation of methyl orange, Ionics, 23 (2017) 1921-1925. https://doi.org/10.1007/s11581-017-2144-4
Zhou W, Yin Z, Du Y et al., Synthesis of few-layer MoS2 nanosheet-coated TiO2 nanobelt heterostructures for enhanced photocatalytic activities, Small 9 (2013) 140–147. https://doi.org/10.1002/smll.201201161
Yin Z., Chen B., Bosman M., Cao X., Chen J., Zheng B., Zhang H., Au nanoparticle-modified MoS2 nanosheet - based photoelectrochemical cells for water splitting, Small 10 (2014) 3537–3543. https://doi.org/10.1002/smll.201400124
Sara Cravanzola, Federico Cesano, Giuliana Magnacca, Adriano Zecchina, Domenica Scarano, Designing rGO/MoS2 hybrid nanostructures for photocatalytic applications, J. Name . (2013) 1-3. https://doi.org/10.1039/C6RA08633K
Wang Y, Ou JZ, Chrimes AF et al., Plasmon resonances of highly doped two-dimensional MoS2, Nano Lett 15 (2015) 883–890. https://doi.org/10.1021/nl503563g
R. Nasser, H. Elhouichet and M. Férid, Effect of Mn doping on structural, optical and photocatalytic behaviors of hydrothermal Zn1-xMnxS nanocrystals, Appl. Surf. Sci. 351 (2015) 1122 – 1130. https://doi.org/10.1016/j.apsusc.2015.06.096
Ren X., Ma Q., Fan H., Pang L., Zhang Y., Yao Y., Ren X., Liu S., A Se-doped MoS2 nanosheet for
improved hydrogen evolution reaction, Chem Commun 51 (2015) 15997–16000. https://doi.org/10.1039/C5CC06847A
Wei Li, Guojing Wang, Chienhua Chen, Jiecui Liao and Zhengcao Li, Enhanced Visible Light Photocatalytic Activity of ZnO Nanowires Doped with Mn2+ and Co2+ Ions, Nanomaterials, 7 (2017) 20. https://doi.org/10.3390/nano7010020
J. Prasad, A. K. Singh, K. K. Haldar, V. Gupta, K. Singh, Electromagnetic interference shielding effectiveness in 3D flower-like MoS2-rGO/gadolinium-doped nanocomposites, Journal of Alloys and Compounds, 788 (2019) 861-872. https://doi.org/10.1016/j.jallcom.2019.02.246
Liqian Wu, Xiaobing Xu, Yuqi Zhao, Kaiyu Zhang, Yuan Sun, Tingting Wang, Yuanqi Wang, Wei Zhong, Youwei Du, Mn doped MoS2/reduced graphene oxide hybrid for enhanced hydrogen evolution, Applied Surface Science, 425 (2017) 470-477. https://doi.org/10.1016/j.apsusc.2017.06.223
A. Santhana Krishna Kumar, Shiuh-Jen Jiang, and Jolanta Karolina Warchoł, Synthesis and Characterization of Two-Dimensional Transition Metal Dichalcogenide Magnetic MoS2@Fe3O4 Nanoparticles for Adsorption of Cr(VI)/Cr(III), ACS Omega, 2 (2017) 6187−6200. https://doi.org/10.1021/acsomega.7b00757
Jie Liu, Ying Li, Jun Ke, Zhong Wang and Huining Xiao, Synergically Improving Light Harvesting and Charge Transportation of TiO2 Nanobelts by Deposition of MoS2 for Enhanced Photocatalytic Removal of Cr(VI), Catalyst, 7(1) (2017) 30. https://doi.org/10.3390/catal7010030
M. Amini, A.R. S.A, M. Faghihi, S. Fattahpour, Preparation of nanostructured and Nanosheets of MoS2 oxide using oxidation method, Ultrasonics Sonochemistry, 39 (2017) 188-196. https://doi.org/10.1016/j.ultsonch.2017.04.024
Jing Wang, Wentao Zhang, Yanru Wang, Wenxin Zhu, Daohong Zhang, Zhonghong Li, and Jianlong Wang, Enhanced Exfoliation Effect of Solid Auxiliary Agent On the Synthesis of Biofunctionalized MoS2 Using Grindstone Chemistry, Particle and Particle Systems Characterization 33, 11, (2016). https://doi.org/10.1002/ppsc.201600114
Keqing Zhou, Saihua Jiang, Chenlu Bao, Lei Song, Bibo Wang, Gang Tang, Yuan Hu and Zhou Gui, Preparation of poly (vinyl alcohol) nanocomposites with molybdenum disulfide (MoS2): structural characteristics and markedly enhanced properties, RSC Advances, 2 (2012) 11695–11703. https://doi.org/10.1039/C2RA21719H
Tseng, L.-T., Luo, X., Tan, T.T., Li, S., Yi, J., Doping concentration dependence of microstructure and magnetic behaviours in Co-doped TiO2 nanorods. Nanoscale Res. Lett. 9 (1) (2014) 1–10. https://doi.org/10.1186/1556-276X-9-673
M. Ahmad, E. Ahmed, W. Ahmed, A. Elhissi, Z.L. Hong, N.R. Khalid, Enhancing visible light responsive photocatalytic activity by decorating
Mn-doped ZnO nanoparticles on graphene. Ceramics International, 40, 7 (2014) 10085-10097. https://doi.org/10.1016/j.ceramint.2014.03.184
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