Fischer-Tropsch synthesis over Co/g-Al2O3 catalyst loaded on ceramic monolith-structured substrate

Do Pham Noa Uy; Nguyen Manh Huan; Hoang Van Loc; Luc Minh Chien; Nguyen Thi Chau Giang; Truong Van Nhan; Phan Minh Quoc Binh; Nguyen Huu Luong; Huynh Minh Thuan

doi:10.51316/jca.2020.055

Authors

Do Pham Noa Uy Vietnam Petroleum Institute
Nguyen Manh Huan Vietnam Petroleum Institute
Hoang Van Loc PetroVietnam University
Luc Minh Chien PetroVietnam University
Nguyen Thi Chau Giang Vietnam Petroleum Institute
Truong Van Nhan Vietnam Petroleum Institute
Phan Minh Quoc Binh Vietnam Petroleum Institute
Nguyen Huu Luong Vietnam Petroleum Institute
Huynh Minh Thuan Vietnam Petroleum Institute

DOI:

https://doi.org/10.51316/jca.2020.055

Keywords:

Fischer-Tropsch, Monolith structured catalyst, Cobalt-based catalyst, Wash-coating slurry method

Abstract

Cobalt-based catalyst supported on g-Al₂O₃ was prepared by impregnation method and loaded on ceramic monolith-structured substrate by wash-coating slurry method. Physico-chemical properties of the catalysts were characterized by X-ray diffraction (XRD), Brunauer–Emmett–Teller (BET) specific surface area and H₂ temperatured-programmed reduction (H₂-TPR). Activity of the catalysts for Fischer-Tropsch synthesis was investigated in a tubular reactor in a temperature range of 200-275 ^oC at 20 bar and GHSV = 3000 h^-1. Co/g-Al₂O₃ catalyst loaded on ceramic monolith-structured substrate enhanced efficacy of Fischer-Tropsch synthesis by increasing and stabilizing CO conversion and C₅₊ selectivity, compared to Co/g-Al₂O₃ powder catalyst.

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