Highly active hydrogenation of 4-methoxyacetophenone by the novel carbon-supported ternary nanocatalyst palladium-vanadium-cobalt

PGS. Cổ Thanh Thiện - ĐHQG HCM; To Kim Can; Diep Thi Duyen; Nguyen Thi Yen Nhi; Nguyen Thuan Khiet Trinh; Mai Tuyet Mai; Hoang Cong Lam Trieu; Tran Thi Ngoc Quynh; Nguyen Van Kien

doi:10.62239/jca.2024.007

Authors

Co Thanh Thien University of Science, Vietnam National University, Ho Chi Minh City, VIETNAM
To Kim Can University of Science, Ho Chi Minh City, VIETNAM
Diep Thi Duyen University of Science, Ho Chi Minh City, VIETNAM
Nguyen Thi Yen Nhi University of Science, Vietnam National University, Ho Chi Minh City, VIETNAM
Nguyen Thuan Khiet Trinh University of Science, Ho Chi Minh City, Vietnam
Mai Tuyet Mai University of Science, Ho Chi Minh City, Vietnam
Hoang Cong Lam Trieu University of Science, Ho Chi Minh City, Vietnam
Tran Thi Ngoc Quynh University of Science, Ho Chi Minh City, Vietnam
Nguyen Van Kien University of Science, Ho Chi Minh City, Vietnam

DOI:

https://doi.org/10.62239/jca.2024.007

Keywords:

Nanocatalysts, palladium, cobalt, vanadium, hydrogenation

Abstract

Multimetallic nanocatalysts have remarkably revealed activities in various catalytic applications. Herein, the ternary nanocatalysts based on palladium-vanadium-cobalt were successfully synthesized through the reduction of their salts with sodium borohydride including impregnating of activated carbon (AC) substrate with colloid solution of metallic nanoparticles (PdVCo/C). The immobile of trimetallic PdVCo on AC was evidenced by XRD, scanning electron microscopy (SEM), transmission electron microscopy (TEM) and UV-VIS spectroscopy. TEM imaging showed that the PdVCo particles size is about 7 nm. The trimetallic nanocatalysts were characterized in transfer hydrogenation of carbonyl substrates to alcohol product which was defined by GC (FID detector). The obtained result is that the conversion of the carbonyl substrates is over 73% in the case of PdVCo nano-catalyst in the presence of potassium hydroxide.

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