Study on the removal of Rhodamine B of Iron(III)-dicarboxylic framework/graphene nanoplatelets composites
DOI:
https://doi.org/10.51316/jca.2023.048Keywords:
MOFs, GNPs, isotherm, kineticsAbstract
In this study, Iron(III)-dicarboxylic framework/graphene nanoplatelets (Fe-BDC/GNPs) composites were synthesized by the ultrasonic method in a water/ethanol mixture solvent. As-prepared composite materials were characterized by XRD, SEM, BET, and laser light scattering techniques. The sorption behaviors of Rhodamine B by the prepared material were studied. The results showed that the material could effectively remove chromogenic organic compounds (RhB) by the adsorption process. The prepared Fe-BDC/GNPs composite revealed high adsorption toward RhB with removal percentage of higher 90% at an RhB initial concentration of 10 ppm after 2 hours. The Freundlich isotherm was more suitable than the Langmuir isotherm and Temkin isotherm for the adsorption process of Rhodamine B onto the synthesized material with R2 = 0,9955. The analytical outputs also revealed that the adsorption kinetics were more accurately represented by the second-order model as both R2 = 0,9974 and qe,cal was approximate to qe,exp.
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