Study on photocatalytic degradation of methylene blue by TiO2 synthesiszed from titanium slag using a new decomposition agent

Authors

  • Tran Van Chinh Institute of Chemistry and Materials, Academy of Military Science and Technology Author
  • Tran Thi Hien Anh Hanoi National University of Education Author
  • Ha Thi Cam Tu Hanoi National University of Education Author
  • Hoai Viet Truong Military Technical Academy Author
  • Nguyen Thi Hoai Phuong Institute of Chemistry and Materials, Academy of Military Science and Technology Author
  • Ho Phuong Hien Hanoi National University of Education Author
  • La Duc Duong Institute of Chemistry and Materials, Academy of Military Science and Technology Author

DOI:

https://doi.org/10.51316/jca.2022.013

Keywords:

Titanium slag, photocatalysts, dye

Abstract

This paper describes a novel process for the synthesis of TiO2 from titanium slag, which is realized via roasting titanium slag with KHSO4, acid leaching and hydrolysis. The results showed that the optimum conditions were a mass ratio of KHSO4 to titanium slag of 6, a temperature of 600 oC for 1,5 hours. Besides, this study investigated the possibility of synthesized TiO2 for photocatalytic degradation of methylene blue.

Downloads

Download data is not yet available.

References

Meng A, Zhang L, Cheng B, Yu J. Dual cocatalysts in TiO2 photocatalysis. Advanced Materials. 31(30) (2019) 1807660. https://doi.org/10.1002/adma.201807660

Al-Mamun M, Kader S, Islam M, Khan M. Photocatalytic activity improvement and application of UV-TiO2 photocatalysis in textile wastewater treatment: A review. Journal of Environmental Chemical Engineering. 7(5) (2019) 103248. https://doi.org/10.1016/j.jece.2019.103248

Khore SK, Kadam SR, Naik SD, Kale BB, Sonawane RS. Solar light active plasmonic Au@TiO2 nanocomposite with superior photocatalytic performance for H2 production and pollutant degradation. New Journal of Chemistry. 42(13) (2018) 10958-68. https://doi.org/10.1039/C8NJ01410H

Fagan R, McCormack DE, Dionysiou DD, Pillai SC. A review of solar and visible light active TiO2 photocatalysis for treating bacteria, cyanotoxins and contaminants of emerging concern. Materials Science in Semiconductor Processing 42 ( 2016) 2-14.

https://doi.org/10.1016/j.mssp.2015.07.052

Janisch R, Gopal P, Spaldin NA. Transition metal-doped TiO2 and ZnO—present status of the field. Journal of Physics: Condensed Matter. 17(27):R657 (2005).

https://doi.org/10.1088/0953-8984/17/27/R01

Basavarajappa PS, Patil SB, Ganganagappa N, Reddy KR, Raghu AV, Reddy CV. Recent progress in metal-doped TiO2, non-metal doped/codoped TiO2 and TiO2 nanostructured hybrids for enhanced photocatalysis. International Journal of Hydrogen Energy. 45(13) (2020) 7764-78. https://doi.org/10.1016/j.ijhydene.2019.07.241

Tuan TN. Synthesis and characterization of gnps/ti-fe binary oxide composite from ilminite of central viet nam using hydrothermal method. Vietnam Journal of Science Technology. 56(2A) (2018) 1-10.

Pan X, Zhao Y, Liu S, Korzeniewski CL, Wang S, Fan Z, et al. Comparing graphene-TiO2 nanowire and graphene-TiO2 nanoparticle composite photocatalysts. ACS applied materials. 4(8) (2012) 3944-50. https://doi.org/10.1021/am300772t

Nguyen KC, Ngoc MP, Van Nguyen M. Enhanced photocatalytic activity of nanohybrids TiO2/CNTs materials. Materials Letters. 165 (2016) 247-51. https://doi.org/10.1016/j.matlet.2015.12.004

Helmy ET, El Nemr A, Mousa M, Arafa E, Eldafrawy S. Photocatalytic degradation of organic dyes pollutants in the industrial textile wastewater by using synthesized TiO2, C-doped TiO2, S-doped TiO2 and C, S co-doped TiO2 nanoparticles. Journal of Water Environmental Nanotechnology. 3(2) (2018) 116-27. https://doi.org/10.22090/JWENT.2018.02.003

Ohno T, Mitsui T, Matsumura M. Photocatalytic activity of S-doped TiO2 photocatalyst under visible light. Chemistry letters. 32(4) (2003) 364-5. https://doi.org/10.1246/cl.2003.364.

Umebayashi T, Yamaki T, Tanaka S, Asai K. Visible light-induced degradation of methylene blue on S-doped TiO2. Chemistry letters. 32(4) (2003) 330-1.

Ohno T, Akiyoshi M, Umebayashi T, Asai K, Mitsui T, Matsumura M. Preparation of S-doped TiO2 photocatalysts and their photocatalytic activities under visible light. Applied Catalysis A: General. 265(1) (2004) 115-21. https://doi.org/10.1016/j.apcata.2004.01.007

Xiong X, Wang Z, Wu F, Li X, Guo H. Preparation of TiO2 from ilmenite using sulfuric acid decomposition of the titania residue combined with separation of Fe3+ with EDTA during hydrolysis. Advanced Powder Technology. 24(1) (2013) 60-7. https://doi.org/10.1016/j.apt.2012.02.002

Razavi R, Hosseini SMA, Ranjbar M, Engineering C. Production of nanosized synthetic rutile from ilmenite concentrate by sonochemical HCl and H2SO4 leaching. Iranian Journal of Chemistry. 33(2) (2014) 29-36. https://doi.org/10.30492/IJCCE.2014.10749

Hanum Lalasari L, Firdiyono F, Herman Yuwono A, Harjanto S, Suharno B, editors. Preparation, Decomposition and Characterizations of Bangka-Indonesia Ilmenite (FeTiO3) derived by Hydrothermal Method using Concentrated NaOH Solution. Advanced Materials Research; Trans Tech Publ (2012). https://doi.org/10.4028/www.scientific.net/AMR.535-537.750

Wang D, Chu J, Liu Y, Li J, Xue T, Wang W, et al. Novel process for titanium dioxide production from titanium slag: NaOH-KOH binary molten salt roasting and water leaching. Industrial Engineering Chemistry Research. 52(45) (2013) 15756-62. https://doi.org/10.1021/ie400701g

Liu Y, Qi T, Chu J, Tong Q, Zhang Y. Decomposition of ilmenite by concentrated KOH solution under atmospheric pressure. International journal of mineral processing. 81(2) (2006) 79-84. https://doi.org/10.1016/j.minpro.2006.07.003

Liu W, Wang X, Lu Z, Yue H, Liang B, Lü L, et al. Preparation of synthetic rutile via selective sulfation of ilmenite with (NH4)2SO4 followed by targeted removal of impurities. Chinese journal of chemical engineering. 25(6) (2017) 821-8. https://doi.org/10.1016/j.cjche.2016.10.007

Chinh TV, Phương NTH. Nghiên cứu chế tạo TiO2 từ quặng ilmenit bằng phương pháp hyđrosunfat. Tạp chí Khoa học và Công nghệ Việt Nam (2017) 14(3).

Ullah H, Viglašová E, Galamboš M. Visible Light-Driven Photocatalytic Rhodamine B Degradation Using CdS Nanorods. Processes. 9(2) (2021) 263. https://doi.org/10.3390/pr9020263

Published

30-04-2022

Issue

Section

Full Articles

How to Cite

Study on photocatalytic degradation of methylene blue by TiO2 synthesiszed from titanium slag using a new decomposition agent. (2022). Vietnam Journal of Catalysis and Adsorption, 11(1), 88-92. https://doi.org/10.51316/jca.2022.013

Share

Most read articles by the same author(s)

Similar Articles

1-10 of 82

You may also start an advanced similarity search for this article.