PolyTEMPO electrocatalyst for organic electrosynthesis of benzonitrile from benzyl alcohol

Luyen Thi Tran; Benjamin Schille; Robert Francke

doi:10.51316/jca.2021.015

Authors

Luyen Thi Tran School of Chemical Engineering, Hanoi University of Science and Technology, Hanoi, Vietnam Author
Benjamin Schille Institute of Chemistry, University of Rostock, Rostock, Germany Author
Robert Francke Institute of Chemistry, University of Rostock, Rostock, Germany Author

DOI:

https://doi.org/10.51316/jca.2021.015

Keywords:

PolyTEMPO, Electrocatalyst, Electrosynthesis, Benzonitrile, Benzyl alcohol

Abstract

Requirements for using Poly (2,2,6,6-tetramethylpiperidinyloxy-4-yl methacrylate) (PolyTEMPO) as an electrocatalyst for the organic electrosynthesis of benzonitrile from benzyl alcohol were investigated. The research results indicated that PolyTEMPO expressed catalytic activity in the electrosynthesis of benzonitrile from benzyl alcohol in the presence of ammonium acetate. The electrosynthesis yield of benzonitrile from benzyl alcohol with PolyTEMPO catalyst reached the maximum value at 35 °C after 18 hours.

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