Determination of the potential byproduct in the toluene oxidation process by CuMnOx catalyst on cordierite substrate

Tran Thị Thu Hien; Vu Duc Hiep; Nguyen Van Chuc; Khong Manh Hung; Ly Bich Thuy; Le Minh Thang

doi:10.51316/jca.2022.041

Determination of the potential byproduct in the toluene oxidation process by CuMnO_x catalyst on cordierite substrate

Authors

Tran Thị Thu Hien School of Environmental Science and Technology, Ha Noi University of Science and Technology, 01 Dai Co Viet, Ha Noi, Viet Nam | Faculty of Natural Sciences , Quy Nhon University, 170 An Duong Vuong, Quy Nhon City, Binh Dinh, Viet Nam
Vu Duc Hiep School of Chemical Engineering, Ha Noi University of Science and Technology, 01 Dai Co Viet, Ha Noi, Viet Nam
Nguyen Van Chuc School of Chemical Engineering, Ha Noi University of Science and Technology, 01 Dai Co Viet, Ha Noi, Viet Nam
Khong Manh Hung School of Chemical Engineering, Ha Noi University of Science and Technology, 01 Dai Co Viet, Ha Noi, Viet Nam
Ly Bich Thuy School of Environmental Science and Technology, Hanoi University of Science and Technology
Le Minh Thang School of Chemical Engineering, Ha Noi University of Science and Technology, 01 Dai Co Viet, Ha Noi, Viet Nam

DOI:

https://doi.org/10.51316/jca.2022.041

Keywords:

CuMnOx, toluene, impregnation method, by-products

Abstract

Cordierite is the substrate that posseses a low thermal expansion coefficient, good thermal shock resistance, excellent mechanical properties, and chemical resistance. Thus, cordierite is widely used as substrate for catalysts in high-temperature applications like gaseous treatment. CuMnO_x/cordierite catalyst for the complete oxidation of toluene was prepared by the impregnation method and characterized by XRD, BET, IR techniques. This work evaluated the catalytic activity of the prepared catalyst at the temperature range from 150^oC to 350^oC. It was found that CuMnO_x/cordierite catalyst completely converted toluene to CO₂ at 350^oC. In addition, the mechanism of the toluene oxidation process using CuMnO_x/cordierite catalyst was also determined via the indentification of the presentation of the by-products by GC/MS technique at various reaction temperature of 200^oC, 250^oC, and 350^oC. The results showed that the reaction over the CuMnO_x/cordierite catalyst followed the same mechanism as proposed by Lars and Andersson. The intermediate products of the oxidation process at 200^oC, 250^oC, and 350^oC were benzyl alcohol, benzaldehyde, benzoic acid, benzene, phenol, 1.4-hydroquinone, 1,4- benzoquinone, and maleic anhydride.

Downloads

Download data is not yet available.

References

M. S. Kamal, S. A. Razzak, M. M. Hossain, Atmospheric Environment 140 (2016) 117-134. https://doi.org/10.1016/j.atmosenv.2016.05.031

C. Lahousse, A. Bernier, E. Gaigneaux, P. Ruiz P, P. Grange, B. Delmon, Proceedings of the 3rd World Congress on Oxidation Catalysis 1997 777–785. http://doi.org/10.1016/s0167-2991(97)81040-3

J. Luo., Q. Zhang, A. Huang, S. L. Suib, Microporous and Mesoporous Materials, 35 (2000), 209–217. http://doi.org/10.1016/s1387-1811(99)00221-8.

F. N. Aguero, A. Scian, B. P. Barbero, L. E. Cadús., Catalysis Today 133 (2008) 493–501.

http://doi.org/10.1016/j.cattod.2007.11.044

H. Einaga, S. Yamamoto, N. Maeda, Y. Teraoka, Catalysis Today, 242 (2015) 287–293.

http://doi.org/10.1016/j.cattod.2014.05.018

Q. Sun, L. Li, H. Yan, X. Hong, K.S. Hui, Z. Pan, Chemical Engineering Journal 242 (2014) 348–356. http://doi.org/10.1016/j.cej.2013.12.097

L.Naleki, M. Haghshenas Frad, M. Khoshnoodi, A. A. Mirzaei, G. J. Hutching, S. H. Taylor, Iranian Journal of Chemical Engineering 1 (2004) 11 -18.

S. Behar, P. Gonzalez, P. Agulhon, F. Quignard, D. Swierczy ´nski, Catalysis Today 189 (2012) 35–41. https://doi.org/10.1016/j.cattod.2012.04.004

B. D. Napruszewska, A. Michalik, A. Walczyk, D. Duraczy ´nska, R. Dula, W. Rojek, L. Lity ´nska-Dobrzy ´nska, K. Bahranowski, E. M. Serwicka, Materials 11 (2018). https://doi.org/10.3390/ma11081365

T. J. Clarke, S. A. Kondrat, S. H. Taylor, Catalysis Today 258 (2015) 610-615.

M. R. Morales, B. P. Barbero, L. E. Cadús, Applied Catalysis B: Environmental 67 (2006) 229–236. http://doi.org/10.1016/j.apcatb.2006.05.006.

N. E. Ntainjua, S. H. Taylor, Topics in Catalysis, 52 (2009) 528–541. https://doi.org/10.1007/s11244-009-9180-x.

H.C. Genuino, S. Dharmarathna, E.C. Njagi, M.C. Mei, S.L. Suib, The Journal of Physical Chemistry C 116 (2012) 12066-12078. https://doi.org/10.1021/jp301342f

R. G. Akay, A. B. Yurtcan, Direct Liquid Fuel Cells: Fundamentals, Advances and Future, Elsevier 2020 https://doi.org/10.1016/C2018-0-04168-7.

G. Allen, J.C. Bevington, Comprehensive polymer science and supplements, Elsevier, 1996, https://doi.org/10.1016/B978-0-08-096701-1.00181-6.

T. Tsoncheva, G. Issa, I. Genova, M. Dimitrov, Journal of Porous Materials 20 (2013) 1361–1369. https://doi.org/10.1007/s10934-013-9722-2.

D. Fang, J. Xie, D. Mei, Y. Zhang, F. He, X. Liu, Y. Li, RSC Advances 4 (2014).

https://doi.org/10.1039/c4ra02824d

N. R. E. Radwan, G. A. El-Shobaky, Y. M. Fahmy, Applied Catalysis A: General 274 (2004) 87–99. https://doi.org/10.1016/j.apcata.2004.05.032.

M. Rundans, G. Sedmale, I. Sperberga, I. Pundiene, Advances in Science and Technology 89 (2014) 94–99. http://doi.org/10.4028/www.scientific.net/as

T. M. P. Phạm, Q. M. Nguyễn, T.T. Nguyễn, I. Van Driessche, M.T. Lê, Investigating the different methods of cordierite's preparation to apply in three-way catalysts manufacture, Materials 50(2012), 135 – 138. https://doi.org/10.3390/ma7096237

T. T. H. Tran, B. T. Ly, T. M. P. Pham, M. T. Le, Vietnam Journal of Catalysis and Adsorption, 10 (2021). https://doi.org/10.51316/jca.2021.068

D. MubarakAli, J. Arunkumar, P.Pooja, G. Subramanian, N. Thajuddin, N. S. Alharbi, Saudi Pharmaceutical Journal 23 (2015) 421–428. http://doi.org/10.1016/j.jsps.2014.11.007.

D. Zhu, L. Wang, W.Yu, H.Xie, Scientific reporters 8(2018). https://doi.org/10.1038/s41598-018-23174-z

N. Benreguia., A. Barnabé, M. Trari, Materials Science in Semiconductor Processing 56 (2016) 14–19. http://doi.org/ 10.1016/j.mssp.2016.07.012.

L. Wang, M. Arif , G. Duan, S. Chen, X. Liu, Journal of Power Sources 355 (2017) 53–61.

http://doi.org/10.1016/j.jpowsour.2017.04.05.

L. Cai, Z. Hu, P. Branton, W. Li W, Chinese Journal of Catalysis 32 (2014) 159–167.

http://doi.org/10.1016/s1872-2067(12)60699-8.

L. Kang, M. Zhang, Z. H. Liu, K. Ooi, Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy, 67 (2007) 864–869. http://doi.org/10.1016/j.saa.2006.09.001.

S. Dey, G. C. Dhal, D. Mohan, R. Prasad, Bulletin of Chemical Reaction Engineering & Catalysis, 12 (2017) 393-40. http://doi.org/10.9767/bcrec.12.3.882.393-407.

Z. Tian., W. J. Pitz, R. Fournet, P. A. Glaud, F. Battin-Leclerc, Proceedings of the Combustion Institute 33 (2011) 233–241. http://doi.org/10.1016/j.proci.2010.06.063

Y. Ji, J. Zhao, H. Terazono, K. Misawa, N. P. Levitt, Y. Li, … R. Zhang, Proceedings of the National Academy of Sciences 114 (2017), 8169–8174. http://doi.org/10.1073/pnas.1705463114

J. A. A. Hoorn, P. L. Alsters, G. F. Versteeg, International Journal of Chemical Reactor Engineering 3 (2005). http://doi:org/10.2202/1542-6580.1196

R. Wu, S. Pan, Y. Li, L. Wang (2014), The Journal of Physical Chemistry A 118 (2014) 4533–4547. http://doi.org/10.1021/jp500077f

S. L. T. Andersson, Journal of Chromatographic Science 23 (1985) 17–21. http://doi:org/10.1093/chromsci/23.1.17

G. Xiao, W. Xu, R. Wu, M. Ni, C. Du, X. Gao, Z. Y. Luo, K. Cen, Plasma Chemistry and Plasma Processing 34 (2014) 1033–1065. http://doi:org/ 10.1007/s11090-014-9562-0

X. Li, J. Xu, F. Wang, J. Gao, L. Zhou., G. Yang, Catalysis Letters 108 (2006) 137–140. https://doi.org/10.1007/s10562-006-0034-x

Downloads

PDF - Fulltext

Published

30-10-2022

Issue

Vol. 11 No. 3 (2022): October

Section

Full Articles

How to Cite

Determination of the potential byproduct in the toluene oxidation process by CuMnOx catalyst on cordierite substrate. (2022). Vietnam Journal of Catalysis and Adsorption, 11(3), 1-7. https://doi.org/10.51316/jca.2022.041