Cu2(BDC)2DABCO as an efficient heterogeneous catalyst for the oxidative C-N coupling reaction between amides and unactivated alkanes
DOI:
https://doi.org/10.51316/jca.2020.011Keywords:
Metal-organic frameworks, catalysis, oxidative C-N couplingAbstract
A copper-organic framework Cu2(BDC)2DABCO was synthesized, and used as a recyclable heterogeneous catalyst for C-N coupling reaction between benzamide and cyclohexane. 94% yield of N-cyclohexylbenzamide was achieved under the optimized condition. The copper-organic framework catalyst was truly heterogeneous and could be used at least 4 cycles without degradation of catalytic performance. To the best of our knowledge, the amidation of unactivated alkanes by benzamides via direct oxidative C-N coupling was previously performed under heterogeneous catalysis conditions but very rare.
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