Synthesis of nano-ZIF-90 from zinc sulfate heptahydrate and evaluation of its stability for use as a cancer drug carrier
DOI:
https://doi.org/10.62239/jca.2025.052Keywords:
ZIF-90; zinc sulfate heptahydrate; synthesis; characterization; cancer drug carrierAbstract
The paper presents the first research results on the synthesis of nano-ZIF-90 from zinc sulfate heptahydrate at room temperature. The factors of solvent composition, crystallization time and repeatability of the synthesis process of nano-ZIF-90 from ZnSO4.7H2O have been reported. The stability of synthesized nano-ZIF-90 according to temperature and environmental pH to be used as a drug carrier for cancer treatment is also discussed. XRD, F-TIR, SEM, TEM, BET and DTA/TGA methods have been used to characterize the structure and properties of the studied samples. The synthesized nano-ZIF-90 material has crystallinity of 100 % (by XRD), specific surface area of 468 m2/g (by BET), crystal size of 43 nm (by TEM), and thermal stability up to 250 oC. In particular, it was determined that at pH = 5.5, the nano-ZIF-90 structure began to break down, increasing the ability to deliver cancer-targeted anti-cancer drugs due to structural collapse when using nano-ZIF-90 as a drug carrier.
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Copyright (c) 2025 Ta Ngoc Thien Huy, Le Van Duong, Tran Thi Thao Vy, Le Ngoc Duong, Bui Thi Thanh Ha, Trinh Xuan Bai, Nguyen Thi Linh, Nguyen Thi Hong Phuong, Ta Ngoc Don
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