Research on synthesizing nano-ZIF-94 from zinc nitrate hexahydrate in ethanol without additional substances

Trinh Thi Hai; Trần Thị Thảo Vy Ta; Lê Ngọc Dương; Nhữ Thị Thảo; Phạm Thị Mai Hương; Tạ Ngọc Thiện Huy; Lê Nguyễn Thanh Long; Nguyễn Thị Minh Thu; Lê Văn Dương; Ta Ngoc Don

doi:10.62239/jca.2025.022

Authors

Trinh Thi Hai Hanoi University of Industry
Tran Thi Thao Vy Nha Trang University
Le Ngoc Duong Hanoi Dong Do International University
Nhu Thi Thao School of Chemistry and Life Sciences, Hanoi University of Science and Technology
Pham Thi Mai Huong Hanoi University of Industry
Ta Ngoc Thien Huy Kien Giang University
Le Nguyen Thanh Long School of Chemistry and Life Sciences, Hanoi University of Science and Technology
Nguyen Thi Minh Thu School of Chemistry and Life Sciences, Hanoi University of Science and Technology
Le Van Duong School of Chemistry and Life Sciences, Hanoi University of Science and Technology
Ta Ngoc Don School of Chemistry and Life Sciences, Hanoi University of Science and Technology

DOI:

https://doi.org/10.62239/jca.2025.022

Keywords:

ZIF-90, zinc nitrate hexahydrate, synthesis, characterization

Abstract

This article presents the first research results on synthesizing ZIF-94 from zinc nitrate hexahydrate in ethanol solvent without adding any other substances.

Experimental sample was studied by modern physicochemical methods such as XRD, F-TIR, SEM, TEM, BET, DTA. The successfully synthesized ZIF-94 has a specific surface area (BET) of 565 m²/g, particle size of 60 nm and heat stable up to 310 ^oC and efficiency of 68.6 %. The research results open up a good opportunity to synthesize ZIF-94 from zinc nitrate hexahydrate in environmentally friendly solvent for application in the fields of adsorption and catalysis in Vietnam.

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