Synthesis and ability to detect Fe3+ ion of N-doped Graphene Quantum Dots materials

Do Van Kiem; Nguyen Tien Dung; Le Huy Nguyen; Bui Thi Lan Phuong; Hoang Nhu Van

doi:10.51316/jca.2022.073

Authors

Do Van Kiem Hanoi National University of Education Author
Nguyen Tien Dung Hanoi National University of Education Author
Le Huy Nguyen Hanoi National University of Education Author
Bui Thi Lan Phuong Hanoi National University of Education Author
Hoang Nhu Van Phenikaa University Author

DOI:

https://doi.org/10.51316/jca.2022.073

Keywords:

Nitrogen-doped graphene quantum dots, Fe3+, Hydrothermal method

Abstract

In this study, nitrogen-doped graphene quantum dots (N-GQDs) were successfully synthesized by hydrothermal method. The morphology and adsorption properties of samples were studied through high resolution transmission electron microscopy (HR-TEM) and UV-Vis absorption spectra. The UV-Vis absorption spectra showed that the typical absorption peaks at 234 nm and 342 nm and 640 nm were characteristic of the N-GQDs materials. HR-TEM image showed that the average size of N-GQDs is about 5 nm. Compared with the absorption peak at 342 nm (strongest absorption peak) of N-GQDs, the absorption peak of N-GQDs·Fe³⁺ shift towards lower wavelengths at 295 nm, which is due to the complexation between hydroxyl, carboxyl, pyridinic nitrogengroups of the N-GQDs and Fe³⁺ ions. These results indicated that the N-GQDs materials could have potential application for detecte Fe³⁺ in the water.

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