Catalytic activities for the complete oxidation of toluene over MnO2, Co3O4 and NiO catalysts

Tuan Nguyen; Hang Phan

doi:10.51316/jca.2020.014

Authors

Nguyen Dinh Minh Tuan The University of Danang Author
Phan Thi Hang Nga The University of Danang Author

DOI:

https://doi.org/10.51316/jca.2020.014

Keywords:

MnO2, Co3O4, NiO, VOCs, toluene

Abstract

In this study, the catalytic performances of the complete oxidation of toluene over different transition metal oxides including MnO₂, Co₃O₄ and NiO were investigated. These oxides were synthesized by hydrothermal method, followed by annealing. The catalysts were characterized by X-ray diffraction (XRD), Scanning Electron Microscope (SEM) and Nitrogen isotherm adsorption-desorption before being evaluated their catalytic activity for the total oxidation of toluene in air. As a result, MnO₂ was illustrated as the best catalyst having largest surface area and lowest activation energy, followed by Co₃O₄ and NiO.

Downloads

Download data is not yet available.

References

H. Huang, Y. Xu, Q. Feng, D.Y.C. Leung, Catal. Sci. Technol. 5 (2015) 2649–2669. https://doi.org/10.1039/C4CY01733A

J. Li, H. Liu, Y. Deng, G. Liu, Y. Chen, J. Yang, Nanotechnol. Rev. 5 (2016), 147-181. https://doi.org/10.1515/ntrev-2015-0051

C. He, J. Cheng, X. Zhang, M. Douthwaite, S. Pattisson, Z. Hao, Chem. Rev. 119 (2019) 4471–4568. https://doi.org/10.1021/acs.chemrev.8b00408

X. Tang, P.K. Misztal, W.W. Nazaroff, A.H. Goldstein, Environ. Sci. Technol. 50 (2016) 12686–12694. https://doi.org/10.1021/acs.est.6b04415

E. Cetin, M. Odabasi, R. Seyfioglu, Sci. Total Environ. 312 (2003) 103–112. https://doi.org/10.1016/S0048-9697(03)00197-9

K. Tzortzatou, E. Grigoropoulou, J. Environ. Sci. Heal. Part A 45 (2010) 534–541. https://doi.org/10.1080/10934521003595027

J.C. Ge, H.Y. Kim, S.K. Yoon, N.J. Choi, Fuel 218 (2018) 266–274. https://doi.org/10.1016/j.fuel.2018.01.045

Spengler, J. D., Samet, J. M., & McCarthy, J. F. (2001). Indoor air quality handbook (pp. 9-1). New York: McGraw-Hill.

Wallace, L. A. (2001). Assessing human exposure to volatile organic compounds. Indoor Air Quality Handbook. McGraw-Hill.

Y. Chang and J. G. McCarty, Catal. Today, 30 (1996) 163-170. https://doi.org/10.1016/0920-5861(95)00007-0

V. P. Santos, M. F. R. Pereira, J. J. M. Orfao and J. L. Figueiredo, Appl. Catal., B, 99 (2010) 353-363 https://doi.org/10.1016/j.apcatb.2010.07.007

B. Bai, H. Arandiyan, J. Li, Appl. Catal. B Environ. 142–143 (2013) 677–683. https://doi.org/10.1016/j.apcatb.2013.05.056

Y. Li, W. Shen, Chem. Soc. Rev. 43 (2014) 1543–1574. https://doi.org/10.1039/C3CS60296F

C.Y. Ma, Z. Mu, J.J. Li, Y.G. Jin, J. Cheng, G.Q. Lu, Z.P. Hao, S.Z. Qiao, J. Am. Chem. Soc. 132 (2010) 2608–2613. https://doi.org/10.1021/ja906274t

Z. Zhang, Z. Jiang, W. Shangguan, Catal. Today 264 (2016) 270–278. https://doi.org/10.1016/j.cattod.2015.10.040

M.S. Kamal, S.A. Razzak, M.M. Hossain, Atmos. Environ. 140 (2016) 117–134. https://doi.org/10.1016/j.atmosenv.2016.05.031

M. Dixit, G.N. Subbanna, P.V. Kamath, J. Mater. Chem. 6 (1996) 1429–1432. https://doi.org/10.1039/JM9960601429

W. He, X. Li, S. An, T. Li, Y. Zhang, J. Cui, Sci. Rep. 9 (2019) 10838. https://doi.org/10.1038/s41598-019-47120-9

F. Shi, F. Wang, H. Dai, J. Dai, J. Deng, Y. Liu, G. Bai, K. Ji, C.T. Au, Appl. Catal. A Gen. 433–434 (2012) 206–213. https://doi.org/10.1016/j.apcata.2012.05.016

C.T. Wong, A.Z. Abdullah, S. Bhatia, J. Hazard. Mater. 157 (2008) 480–489. https://doi.org/10.1016/j.jhazmat.2008.01.012

B. Miranda, E. Díaz, S. Ordóñez, A. Vega, F. V Díez, Chemosphere 66 (2007) 1706–15. https://doi.org/10.1016/j.chemosphere.2006.07.016

M. Florea, M. Alifanti, V.I. Parvulescu, D. Mihaila-Tarabasanu, L. Diamandescu, M. Feder, C. Negrila, L. Frunza, Catal. Today 141 (2009) 361–366. https://doi.org/10.1016/j.cattod.2008.05.005