Sacrificial template accelerated hydrolysis synthesis of high surface area stainless steel wire mesh-supported zinc-based mixed oxides: ZnCo2O4, Zn2MnO4 and Zn0.3Ni0.7O4
Abstract
The present work reports for the first time the room-temperature synthesis of stainless steel wire-mesh (SSWM) supported spinel metal oxides of high technological interest (ZnCo2O4, Zn2MnO4 and Zn0.3Ni0.7O4) with crystal sizes in the range of 4-8 nm, by applying the sacrificial template-accelerated hydrolysis (STAH) technique. The specific surface area of the spinel metal oxides obtained is at least one order of magnitude higher than that of spinel metal oxides previously obtained by the other technique. The key to achieving this outstanding result was the use of a template (SSWM-supported ZnO nanosheets) with a large proportion of polar surfaces and a high specific surface area (80 m2g-1). The nanosized spinel metal oxides are obtained in high yields (18-26 wt.%), adhere well to the SSWM support and exhibit a high specific surface area (87-178 m2g-1).
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