Influence of some parameters on synthesis processes of triethyl ammonium oleate and triethyl ammonium stearate
DOI:
https://doi.org/10.62239/jca.2024.056Keywords:
ionic liquids, fatty acids, triethyl amine, oleic acid, stearic acidAbstract
Two ionic liquids named triethyl ammonium oleate ([TEA][Oleate] and triethyl ammonium stearate ([TEA][Stearate]) were synthesized from triethyl amine and oleic/stearic acids in water and in ethanol solvents. The synthesized ionic liquids were characterized by FT-IR and NMR spectra to confirm their structure. The influence of some parameters such as structure of ionic liquid anion, solvent, reaction time, reaction temperature, and acid/amine molar ratio on the synthesis processes of triethyl ammonium oleate and triethyl ammonium stearate was investigated. Ethanol was found suitable as a solvent for these processes because it dissolves formed ionic liquids but does not dissolve co-product KCl. In order to shift the equilibrium to increase the ionic liquid yields, an access amount of acids was used. Stearate-based ionic liquid should be synthesized at higher a temperature and longer time than oleic-based ionic liquids.
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