Investigation on synthesis of two ammonium based ionic liquids from fatty acids and triethylamine

Authors

  • Thuy Thi Le Bui Hanoi University of Mining and Geology, Duc Thang, Bac Tu Liem, Ha Noi Author
  • Tien Anh Dang Hanoi University of Mining and Geology, Duc Thang, Bac Tu Liem, Ha Noi Author
  • Khun Borin Hanoi University of Mining and Geology Author
  • Thanh Nam Ly Hanoi University of Mining and Geology, Duc Thang, Bac Tu Liem, Ha Noi Author
  • Trung Tuan Pham Hanoi University of Mining and Geology, Duc Thang, Bac Tu Liem, Ha Noi Author
  • Thanh Xuan Thi Phan Hanoi University of Mining and Geology, Duc Thang, Bac Tu Liem, Ha Noi Author
  • Ngoc Pham-Cong Earlham College, 801 National Rd W, Richmond, IN 47374, United State Author

DOI:

https://doi.org/10.51316/jca.2023.012

Keywords:

Ionic liquid, synthesis, fatty acid, triethyl amine

Abstract

Two ionic liquids triethylammonium oleate and  triethylammonium stearate were synthesized from fatty acids and triethyl amine using two different methods (one step and three step methods). The yield triethylammonium oleate rearch 68.8-74% (one step method) and 86.3% (three step method) and of triethylammonium stearate rearch 68.7-74.1 (one step method) and 83.5% (three step method). The one step method spends more time but less chemicals and brings higher yield. FT-IR and 1H-NMR spectra of ILs obtained from both method was measured. The results showed that synthesis method doesn’t affect on the structure of the products and ILs obtained from one step method has higher purity.

Downloads

Download data is not yet available.

References

María-Dolores Bermúdez, Ana-Eva Jiménez, José Sanes and Francisco-José Carrión, Molecules 14 (2009) 2888-2908. https://10.3390/molecules14082888

Dupont, J. On the solid, J.Braz. Chem. Soc. 15 (2007) 341-350. https://10.1590/s0103-50532004000300002

Brenecke, J.F., Rogers, R.D., Seddon, K.R., Eds.; ACS Symposium Series 975 (2007) 86-101.

https://10.1021/bk-2007-0975.ch007

Consorti, C.S.; Suarez, P.A.Z.; de Souza, R.A.; Farrar, D.H.; Lough, A.J.; Loh, W.; da Silva,

L.H.M.; Dupont, J. Phys. Chem. B 109 (2005) 4341-4349. https://doi.org/10.1021/jp0452709

Ye, C.F.; Liu, W.M.; Chen, Y.X.; Yu, L.G. Chem. Commun. (2001) 2244-2245. https://10.1039/B106935G

Minami, I.; Kamimuram, H.; Mori, J. Synth. Lubr. 24 (2007) 135-147.

https://doi.org/10.1002/jsl.36

Yue Yang, Fanhan Liu, Shaole Song, Honghu Tang, Shitian Ding, Wei Suna, Shuya Lei, Shengming Xu, Lubricants 1 (2013) 3-21, https://doi.org/10.3390/lubricants1010003

Nicole Do¨rr, Proc IMechE Part J: J Engineering Tribology 226 (11) 889–890. https://10.1177/1350650112464332

Jeewan Singh, Sukhpal Singh Chatha, Rakesh Bhatia, Materials Today: Proceedings 56 (2022) 2659–2665. https://10.1016/j.matpr.2021.09.228

Zhaozhao Yang, Bian Guo, Yijing Liang, Qing Huang, Feizhou Li, Ruozheng Wang, Xiaoyan Yan, Bo Yu, Qiangliang Yu, Meirong Cai, Journal of Molecular Liquids 363 (2022) 119837. https://doi.org/10.1016/j.molliq.2022.119837

P. Oulego, D. Blanco, D. Ramos, J.L. Viesca b,c, M. Díaz, A. Hernández Battez, Journal of Molecular Liquids 272 (2018) 937–947, https://doi.org/10.1016/j.molliq.2018.10.106

Tulia Espinosa, José Sanes, Ana-Eva Jiménez, María-Dolores Bermúdez, Wear 303 (2013) 495–509. https://doi.org/10.1016/j.wear.2013.03.041

Ghassan M.J. Al Kaisy, M. Ibrahim A. Mutalib, T V V L N Rao, Adolfo Senatore, Tribology International 160 (2021) 107058.

M.D. Avil´es , R. Pamies , J. Sanes , J. Arias-Pardilla , F.J. Carrion, M.D. Bermúdez, Tribology International 158 (2021) 106917 https://doi.org/10.1016/j.triboint.2021.107058

Raimondas Kreivaitis, Arturas Kupcinskas, Audrius Zunda, Thi Na Ta, Jeng Haur Horng, Wear (2022) 492-493 204217. https://doi.org/10.1016/j.wear.2021.204217

J. L. Viesca, M.T. Mallada b, D. Blanco, A. Fernandez-Gonz alez, J. Espina-Casado c, R. Gonz alez, Tribology International 116 (2017) 422–430. https://doi.org/10.1016/j.triboint.2017.08.004

Bui, T. T. L. A. D. Nguyen, S. Ho-Van and H. T. N. Uong. Journal of Applied Polymer Science 133 (2016) 43920. https://doi.org/10.1002/app.43920

Bui, T. T. L. H. T. N. Uong, L. V. Nguyen and N. C. Pham. Chemical and Biochemical Engineering Quarterly 32 (2018) 41. https:10.15255/CABEQ.2017.1193

Bui, T. T. L, H. T. N. Uong, D. K. Nguyen, D. T. K. Hoang and G. Vo-Thanh. Korean Journal Chemical Engineering 37 (2020) 2262. https://doi.org/10.1007/s11814-020-0659-2

Published

30-03-2023

Issue

Section

Full Articles

How to Cite

Investigation on synthesis of two ammonium based ionic liquids from fatty acids and triethylamine. (2023). Vietnam Journal of Catalysis and Adsorption, 12(1), 74-80. https://doi.org/10.51316/jca.2023.012

Share

Similar Articles

1-10 of 229

You may also start an advanced similarity search for this article.