Synthesis and application of M-BTC (M = Fe, Ni, Mn) materials as highly efficient photocatalyst in the photocatalytic degradation of reactive yellow 145 dye

Nguyen Ba Manh; Le Ha Giang; Pham Thi Thu Trang; Pham Thi Ha My; Duong Anh Thanh; Le Van Dung; Pham Thi Thu Giang; Vu Thi Hoa; Nguyen Ke Quang; Dang Tuyet Phuong

doi:10.51316/jca.2021.146

Authors

Nguyen Ba Manh Institute of Chemistry, Vietnam Academy of Science and Technology Author
Le Ha Giang Institute of Chemistry, Vietnam Academy of Science and Technology Author
Pham Thi Thu Trang Institute of Chemistry, Vietnam Academy of Science and Technology Author
Pham Thi Ha My Institute of Chemistry, Vietnam Academy of Science and Technology Author
Duong Anh Thanh Institute of Chemistry, Vietnam Academy of Science and Technology Author
Le Van Dung Graduate University of Sciences and Technology, Vietnam Academy of Science and Technology Author
Pham Thi Thu Giang Hanoi University of Industry Author
Vu Thi Hoa Hanoi University of Industry Author
Nguyen Ke Quang Institute of Chemistry, Vietnam Academy of Science and Technology Author
Dang Tuyet Phuong Institute of Chemistry, Vietnam Academy of Science and Technology Author

DOI:

https://doi.org/10.51316/jca.2021.146

Keywords:

Fe-BTC, Ni-BTC, Mn-BTC, RY-145, photocatalyst

Abstract

In this study, we synthesized a series of metal organic frameworks (MOFs) of 1,3,5-benzenetricarboxylate (M-BTC), where M = Fe²⁺, Ni²⁺ and Mn²⁺ by hydrothermal treatment with a microwave assisted method. M-BTC samples were characterized by XRD, FTIR, SEM and BET. SEM-image result showed nano M-BTC particles size of 20-40 nm. Samples M-BTC showed the high surface area (1301 m²/g) and pore volume (1.12 cm³/g). The samples M-BTC were tested for the photocatalytic degradation of reactive dye (Reactive Yellow 145) in water. The M-BTC materials exhibited high photocatalytic activity. Thus, at the pH of 6.5 and the high initial concentration of 100 mg RY-145/L, removal efficiency reached the value of 98.63% after 120 min reaction. Moreover, nanomaterial Fe-BTC also showed high RY-145 dye removal efficiency after 4 catalytic regeneration.

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