Study on preparation of nano-ZIF-67 in ethanol
Abstract
In this study, nano crystal ZIF-67 was successfully synthesized at room-temperature using ethanol as solvent. Several factors affecting the synthesis including solvent type, solvent content were investigated. The synthesized nano crystal ZIF-67 was characterized by different techniques such as XRD, FT-IR, SEM, TEM, BET (N2 adsorption - desorption) and TGA/DTA. The Co2+/Hmim/Ethanol molar ratio of 1:8:276 was determined as the most suitable one for the synthesis of nano-ZIF-67 with large BET surface area of 1437,5 m2/g, small crystal size of 50nm, mesopore size (dmeso) of 30nm and high thermal stablity up to 500°C.
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