Synthesis of solid acid-base ZnSn(OH)6 catalyts used for carbonylation of glycerol with urea into glycerol carbonate
Abstract
Zinc hydroxystannate ZnSn(OH)6 a solid acid–base catalyst, was prepared by chemical co-precipitation method using zinc chloride ZnCl2 and tin chloride SnCl4 precursors. Structure and physical properties of ZnSn(OH)6 material was characterized by X-ray diffraction (XRD), the simultaneous thermal analysis (TGA) of the after dried samples, scanning electron microscope (SEM), and acid-base strength of sites catalysts were evaluated by temperature programmed desorption (TPD). The catalyst ZnSn(OH)6was used for carbonylation of glycerol with urea to glycerol carbonate. The activity testing was carried out in the carbonylation of glycerol with urea to glycerol carbonate.
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