Synthesis of MIL-88(Fe) by "green" method for drug delivery purpose
Abstract
MIL-88(Fe), a metal-organic framework material has been synthesized by “green” ultrasound method. The MIL-88(Fe) samples were synthesized from a mixture of ferric chloride and
1,4-benzenedicarboxylic acid (H2BDC) in N,N-dimethylformamide (DMF) at room temperature for 15 mins. The MIL-88(Fe) was characterized by X-ray powder diffraction (XRD) and N2 adsorption porosimetry(BET). MIL-88(Fe) crystals synthesized under ultrasonic condition produced small and homogeneous crystals. The SEM images of the particles synthesized from this method have approximatedimensions of 200-300nm and hexagonal morphologies. This size reduction is typical of crystals synthesized under ultrasonic condition - a phenomenon which can be attributed to make upuniform and rapid nucleations. The small MIL-88(Fe) crystals are especially effective in the drug delivery fields.
Downloads
References
Shilun Qiu, Guangshan Zhu, Coordination Chemistry Reviews 253 (2009) 2891-2911.
Ryan J. Kuppler, Daren J. Timmons, Qian-Rong Fang, Jian-Rong Li, Trevor A. Makal, Mark D. Young, Daqiang Yuan, Dan Zhao, Wenjuan Zhuang, Hong-Cai Zhou, Coordination Chemistry Reviews 253 (2009) 3042-3066.
Yuebo Yu, Yuqian Ren, Wei Shen, Huimin Deng, Zhiqiang Gao, Trends in Analytical chemistry 50 (2013) 33-41.
Akbar Bagheri, Mohsen Taghizadeh, Mohammad Behbahani, Ali Akbar Asgharinezhad, Mani Salarian, Ali Dehghani, Homeira Ebrahimzadeh, Mostafa M. Amini, Talanta 99 (2012) 132-139.
Jesse L.C. Rowsell, Omar M. Yaghi, Microporous and Mesoporous Materials 73 (2004) 3-14.
Patricia Horcajada, Tamim Chalati, Christian Serre, Brigitte Gillet, Catherine Sebrie, Tarek Baati, Jarrod F. Eubank, Daniela Heurtaux, Pascal Clayette, Christine Kreuz, Jong-San Chang, Young Kyu Hwang, Veronique Marsaud, Phuong-Nhi Bories, Luc Cynober, Sophie Gil, Gérard Férey, Patrick Couvreur and Ruxandra Gref, Nature Materials, 9 (2010) 172-178.
Sarwar Beg, Mahfoozur Rahman, Atul Jain, Sumant Saini, Patrick Midoux, Chantal Pichon, Farhan Jalees Ahmad and Sohail Akhter, Drug Discovery Today 22(4) (2017) 625-637.
M. Giménez-Marqués, T. Hidalgo, C. Serre P. Horcajada, Coordination Chemistry Reviews, 307-2 (2016) 342-360.
Hee Jung Lee, Yea Jin Cho, Won Cho, and Moonhyun Oh, ACS Nano 7 (1) (2013) 491-499.
P. Horcajada, F. Salles, S. Wuttke, T. Devic, D. Heurtaux, G. Maurin, A. Vimont, M. Daturi, O. David, E. Magnier, N. Stock, Y. Filinchuk, D. Popov, C. Riekel, G. Férey and C. Serre, Journal of American Chemistry Society 133 (2011) 17839.
C. Gaudin, D. Cunha, E. Ivanoff, P. Horcajada, G. Chevé, A. Yasri, O. Loget, C. Serre, G. Maurin, Microporous and Mesoporous Materials 157 (2012) 124-130.
12. Suzy Surblé, Christian Serre, Caroline Mellot-Draznieks, Franck Millange, Gérard Férey, Supplementary Material (ESI) for Chemical Communications, The Royal Society of Chemistry 2005.
Published
Issue
Section
License
This work is licensed under a Creative Commons Attribution-NonCommercial 4.0 International License.
