Study on properties and oxygen electroreduction of self-assembled binary monolayer of porphyrins deposited on single crystalline Cu(100)
Abstract
A combination of cyclic voltammetry (CV), linear sweep voltammetry (LSV) and in-situ electrochemical scanning tunneling microscopy (EC-STM) was employed to characterize the electrochemical response, morphology and surface structure at the molecular level as well as the electrocatalytic activity of self-assembled binary monolayer of two different porphyrin molecules electrodeposited on Cu(100) electrode. Individual phorphyrin compound locates in separated domains. The mixed domain of both was not observed. Based on the LSV results, this self-assembled binary monolayer enables enhancement the oxygen electroreduction to hydro peroxide (H2O2). This finding opens a new avenue to improve the efficiency of the oxygen electroreduction making use such binary organic molecular self-assemblies.
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