Electrochemical sensor determines antibiotic residues of Chloramphenicol in fresh milk using modified Glassy carbon electrode based on nZVI/GNPs/TCPP nanocomposite material synthesized by green chemistry method

Trung Dung Dang; Nguyen Thuy Trang; Nguyen Thi Xuan Quynh; Nguyen Lan Huong; La Duc Duong

doi:10.62239/jca.2024.025

Authors

Dang Trung Dung School of Chemistry and Life Sciences, Hanoi University of Science and Technology Author
Nguyen Thuy Trang School of Chemistry and Life Sciences, Hanoi University of Science and Technology Author
Nguyen Thi Xuan Quynh School of Chemistry and Life Sciences, Hanoi University of Science and Technology Author
Nguyen Lan Huong School of Chemistry and Life Sciences, Hanoi University of Science and Technology Author
La Duc Duong Institute of Chemistry and Material, Academy of Military Science and Technology Author

DOI:

https://doi.org/10.62239/jca.2024.025

Abstract

Chloramphenicol (CAP) is a broad-spectrum antibiotic widely used in medicine and agriculture since 1948 [1]. Currently, CAP is banned due to its potential health hazards [2]. Therefore, detecting antibiotic residual levels of CAP in food is necessary. The electrochemical method, characterized by its simplicity, speed, high sensitivity, ease of on-site analysis, and low cost, demonstrates potential in assessing antibiotic residual CAP compared to traditional methods such as liquid chromatography-mass spectrometry (LC-MS), liquid chromatography-electrochemical ionization-mass spectrometry (LC-EIS-MS/MS), gas chromatography-mass spectrometry (GC-MS),...[3]. In this study, a material from zero-valent iron nanoparticles combined with graphene nanoplatelets and porphyrin nanofibers (nZVI/GNPs/TCPP) synthesized through green chemistry methods was used as the electrode material to analyze antibiotic residual CAP in fresh milk samples using cyclic voltammetry (CV) and differential pulse voltammetry (DPV), promising results with a limit of detection (LOD) of 0,1212 μM, limit of quantification (LOQ) of 0,4040 μM, and sensitivity of 0,009998 μA.μM^-1.cm^-2.

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