Study on synthesis of mesoporous ZSM-5 zeolite using carboxymethyl cellulose mesopore directing agent for re-arrangement of epoxide
DOI:
https://doi.org/10.51316/jca.2023.025Abstract
This current work presents a study on using carboxylmethyl cellulose (CMC) as mesopore directing agent for synthesis of mesoporous ZSM-5 zeolite. The results showed that CMC, a cellulose derivative can be used as potential mesopore directing agent for synthesis of mesopore zeolite material. The obtained ZSM-5 zeolite was characterized by XRD, SEM methods and was used as catalyst for the isomerization of epoxide to synthesize aldehyde. The synthesized ZSM-5 catalyst exhibited a high catalytic activity and selectivity in the reaction. The highest conversion of about 98,2% was obtained when the isomerization of styrene carried out at suitable reaction conditions.
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Mai Tuyên, Xúc tác zeolit trong hoá dầu, NXB khoa học và kỹ thuật, Hà Nội, 2004.
C.S. Cundy, P.A. Cox, Chem Rev 103 (2003) 663–701.
https://doi.org/10.1021/cr020060i
P.H. Hoang, L.Q. Dien, Chem Eng J 262 (2015) 140–145.
https://doi.org/10.1016/j.cej.2014.09.092
D. Nandan, S.K. Saxenab and N. Viswanadham, J. Mater. Chem. A 2 (2014) 1054-1059. https://doi.org/10.1039/c3ta13904b
H. Tao, C. Li, J. Ren, Y. Wang, G. Lu, Journal of Solid State Chemistry 184 (2011) 1820–1827. https://doi.org/10.1016/j.jssc.2011.05.023.
P.H. Hoang, N.M Dat, Advanced Powder Technology 32 (2021) 3927–3933. https://doi.org/10.1016/j.apt.2021.09.003.
V. Gudla, R. Balamurugan, Tetrahedron Letters (2012) 53 5243–5247.
D. P. Serrano, R. van Grieken, J. A. Melero, A. Garcia, C. Vargas, Journal of Molecular Catalysis A: Chemical 318 (2010) 68–74.
R. van Grieken, D. P. Serrano, J. A. Melero and A. García, J. Mol. Catal. A: Chem 222 (2004) 167-174.
W.F. Hölderich in: R. A. Sheldon, H. van Bekkum (Eds.), Fine Chemicals through Heterogeneous Catalysis, Wiley/VCH, Weinheim, 217 (2001).
K. Smith, G. A. El-Hiti and M. Al-Shamali, Catal. Lett. 109 (2006) 77–82.
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National Foundation for Science and Technology Development
Grant numbers 04.01-2020.14