Enhancing Epoxy Adhesives with CNTs/Gr Hybrid for Advanced Spacecraft Applications

Anh Duc To; Ngoc Minh Phan; Hung Thang Bui

doi:10.62239/jca.2025.011

Authors

To Anh Duc Vietnam National Space Center, Vietnam Academy of Science and Technology https://orcid.org/0000-0002-6279-1560
Phan Ngoc Minh Graduate School of Science and Technology, Vietnam Academy of Science and Technology
Bui Hung Thang Institute of Materials Science, Vietnam Academy of Science and Technology

DOI:

https://doi.org/10.62239/jca.2025.011

Keywords:

Graphene Nanoplatelets, CNTs, Functionalization, Young’s modulus, Flexural modulus

Abstract

The growing demand for advanced materials in small satellite applications, particularly Carbon Fiber Reinforced Polymers (CFRP), underscores the need for innovations in composite components. As epoxy resin forms a key matrix in CFRP, enhancing its properties is crucial for meeting the rigorous demands of space technology. A promising approach involves using functionalized Carbon Nanotubes (CNTs-OH) and Graphene (Gr-COOH) as hybrid fillers. Functional groups improve dispersion, interfacial bonding, and minimize agglomeration within the epoxy matrix, overcoming traditional limitations. Remarkably, these hybrids offer mechanical enhancements comparable to methods like Chemical Vapor Deposition (CVD), while simplifying processing and enabling scalability. Their compatibility with epoxy ensures consistent performance and manufacturability. These functionalized systems represent a significant step toward lightweight, durable, and high-strength materials suitable for extreme environments, aligning with the broader goal of developing advanced CFRP for next-generation small satellites.

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References

R. R. Krishnamoorthy, D. Marius, Appl. Catal. A 121 (2025) 159–206.https://doi.org/10.1016/B978-0-443-221187.00007-5

H. Djojodihardjo, Acta Astronautica (2024). https://doi.org/10.1016/j.actaastro.2024.05.034

J. Yang, Z. Zhu, S. Han, Y. Gu, Z. Zhu, H. Zhang, J. Alloys Compd. 176707 (2024). https://doi.org/10.1016/j.jallcom.2024.176707

I. N. Wani, K. Aggarwal, S. Bishnoi, P. Shukla, D. Harursampath, A. Garg, J. Mater. Res. Technol. 138 (2024). DOI:10.20944/preprints202402.0382.v1.

J. C. Ince, M. Peerzada, L. D. Mathews, A. R. Pai, A. Al-Qatatsheh, S. Abbasi, N. V. Salim, Adv. Compos. Hybrid Mater. 6(4) (2023) 130. https://doi.org/10.1007/s42114-023-00678-5

R. Reda, Y. Ahmed, I. Magdy, H. Nabil, M. Khamis, A. Refaey, G. Abed, Trans. Aerosp. Res. (2023). https://doi.org/10.2478/tar-2023-0016

D. V. Breslavs’kyi, S. O. Pashchenko, O. A. Tatarinova, Strength Mater. 51 (2019) 231–239. https://doi.org/10.1007/s11223-019-00069-6

J. Shen, H. M. Liu, J. Wang, Math. Biosci. Eng. 19 (2022) 2120–2146. DOI: 10.3934/mbe.2022099

A. S. Tsybenko, B. M. Rassamakin, A. A. Rybalka, Strength Mater. 49 (2017) 381–387. https://doi.org/10.1007/s11223-017-9878-0

S. Nasir, M. Z. Hussein, Z. Zainal, N. A. Yusof, Mater. 11(2) (2018) 295. https://doi.org/10.3390/ma11020295

V. K. Thakur, M. K. Thakur, Chem. Funct. Carbon Nanomater. (2018) 5–13. Warentown (NJ: CRC Press. https://doi.org/10.3390/ma11020295

M. Chakraborty, M. S. J. Hashmi, Adv. Mater. Process. Technol. 4(4) (2018) 573–602. https://doi.org/10.1080/2374068X.2018.1484998

G. Zhao, X. Li, M. Huang, Z. Zhen, Y. Zhong, Q. Chen, H. Zhu, Chem. Soc. Rev. 46(15) (2017) 4417–4449. https://doi.org/10.1080/2374068X.2018.1484998

D. G. Papageorgiou, I. A. Kinloch, R. J. Young, Prog. Mater. Sci. 90 (2017) 75–127. https://doi.org/10.1016/j.pmatsci.2017.07.004

Ö. Güler, N. Bağcı, J. Mater. Res. Technol. 9(3) (2020) 6808–6833. https://doi.org/10.1016/j.jmrt.2020.01.077

K. Chu, X. H. Wang, Y. B. Li, D. J. Huang, Z. R. Geng, X. L. Zhao, H. Zhang, Mater. Des. 140 (2018) 85–94. https://doi.org/10.1016/j.matdes.2017.11.048

V. Khanna, V. Kumar, S. A. Bansal, Mater. Res. Bull. 138 (2021) 111224. https://doi.org/10.1016/j.materresbull.2021.111224

K. Chu, F. Wang, X. H. Wang, D. J. Huang, Mater. Sci. Eng. A 713 (2018) 269–277. https://doi.org/10.1016/j.msea.2017.12.080

A. Ali, S. S. R. Koloor, A. H. Alshehri, A. Arockiarajan, J. Mater. Res. Technol. 24 (2023) 6495–6521. https://doi.org/10.1016/j.jmrt.2023.04.072

Y. Lin, Q. Shi, Y. Hao, Z. Song, Z. Zhou, Y. Fu, J. Wu, Int. J. Mech. Sci. 257 (2023) 108532. https://doi.org/10.1016/j.ijmecsci.2023.108532

M. Shifa, F. Tariq, F. Khan, Z. S. Toor, R. A. Baloch, Mater. Res. Express 6(12) (2020) 125629. https://doi.org/10.1088/2053-1591/ab6928

T. S. Jang, J. Rhee, J. K. Seo, Acta Astronaut. 117 (2015) 497–509. https://doi.org/10.1016/j.actaastro.2015.09.014

T. S. Jang, H. K. Cho, H. S. Seo, W. S. Kim, J. H. Rhee, J. Korean Soc. Aeronaut. Space Sci. 38(12) (2010) 1209–1216. https://doi.org/10.5139/JKSAS.2010.38.12.1209

W. Li, A. Dichiara, J. Bai, Compos. Sci. Technol. 74 (2013) 221–227. https://doi.org/10.1016/j.compscitech.2012.11.015

L. Yue, G. Pircheraghi, S. A. Monemian, I. Manas-Zloczower, Carbon 78 (2014) 268–278. https://doi.org/10.1016/j.carbon.2014.07.003

Y. Li, R. Umer, A. Isakovic, Y. A. Samad, L. Zheng, K. Liao, RSC Adv. 3(23) (2013) 8849–8856. https://doi.org/10.1039/C3RA22300K

Sarkar, L., Saha, S., Samanta, R., Sinha, A., Mandal, G., Biswas, A., Das, A., J. Inst. Eng. (India): Ser. D 105(1) (2024) 527–541. https://doi.org/10.1007/s40033-023-00465-y

T. Dutta, I. Llamas-Garro, J. S. Velázquez-González, J. Bas, R. Dubey, S. K. Mishra, IEEE Sens. J. (2024). https://doi.org/10.1109/JSEN.2024.3440499

M. Etesami, M. T. Nguyen, T. Yonezawa, A. Tuantranont, A. Somwangthanaroj, S. Kheawhom, Chem. Eng. J. 446 (2022) 137190. https://doi.org/10.1016/j.cej.2022.137190

C. L. Han, A. L. Zou, G. D. Wang, Y. Liu, N. Li, H. X. Zhang, E. Blackie, Diam. Relat. Mater. 124 (2022) 108953. https://doi.org/10.1016/j.diamond.2022.108953